Published papers

by Hiromi Matsuhashi


2012

Preparation of a novel solid base catalyst of CaO covered with SiO
2
Hiromi Matsuhashi, Anna Kawamura,Catal. Today, 185, 236-240 (2012).


2011

Application of Solid Bases of MgO anf CaO Covered with Al2O3 in Alkylation of Malonates
Yuhki Sakamoto,
Hiromi Matsuhashi, Hideo Nakamura, J. Jpn. Petrol. Inst., 54, 385-389 (2011)

High Temperature-Tolerant Solid Acid of Zirconia Supported on Calcium Oxide
HIromi Matsuhashi, Ryo Tabata, J. Jpn. Petrol. Inst., 54, 272-274 (2011)

Synthesis of a water tolerant solid base of CaO covered with Al
2O3
Hiromi Matsuhashi, Tetsuro Fujita, Catal. Today, 164, 131-134 (2011).



2010

Preferential oligomerization of isobutene in a mixture of isobutene and 1-butene over sodium-modified 12-tungstosilicic acid supported on silica
Jin Zhang, Mitsuru Kanno, Jiao Zhang, Ryuichiro Ohnishi, Kakeru Toriyabe,
Hiromi Matsuhashi, Yuichi Kamiya, J. Mol. Catal. A:Chemical, 326, 107 112 (2010) .

Friedel-Crafts Acylation of Anisole with Phthalic Anhydride Catalyzed by Solid Superacid of Sulfated Zirconia
Hideo Nakamura, Naoko Tanaka, and
Hiromi Matsuhashi, , J. Jpn. Petro. Inst., 53(5), 276-281 (2010).

Surface Base Sites of MgO Covered With Al
2O3: XANES Analysis of Al and Mg K-edges
Hiromi Matsuhashi, Koji Nagashima, Nobuaki Naijo, and Hirofumi. Aritani, Top. Catal., 53, 659-663 (2010).

2009

Characterization of Sulfated Zirconia Prepared Using Reference Catalysts and Application to Several Model Reactions,
Hiromi Matsuhashi, Hideo Nakamura, Tatsumi Ishihara, Shinji Iwamoto, Yuichi Kamiya, Junya Kobayashi, Yoshihiro Kubota, Takashi Yamada, Takeshi Matsuda, Koichi Matsushita, Kazuyuki Nakai, Hiroyasu Nishiguchi, Masaru Ogura, Noriyasu Okazaki, Satoshi Sato, Ken-ichi Shimizu, Tetsuya Shishido, Seiji Yamazoe, Tatsuya Takeguchi, Keiichi Tomishige, Hiromi Yamashita, Miki Niwa and Naonobu Katada, Appl. Catal. A: Gen., 360, 89-97 (2009).

Synthesis of Novel Solid Base of MgO Covered with Metal Oxides,
Hiromi Matsuhashi, Top. Catal., 52, 828-833 (2009).

2008


2007

Increase in the number of acid sites of a H-ZSM5 zeolite during the dehydration of ethanol, Isao Takahara, Masahiro Saito,
Hiromi Matsuhashi, Megumu Inaba, and Kazuhisa Murata, Catal. Lett., 113(3-4), 82-85 (2007).

meta-Stannic acid as an effective support for the preparation of sulfated and tungstated stannias, Makoto Hino, Satoshi Takasaki, Satoshi Furuta,
Hiromi Matsuhashi and Kazushi Arata, Appl. Catal. A: General, 321, 147-154 (2007).

2006

Adsorption and desorption of small molecules for the characterization of solid acids
Hiromi Matsuhashi and Kazushi Arata, Catalysis Surveys from Asia, 10, 1-7 (2006). Abstract

A solid acid of tungsta-niobia more active than aluminosilicates for decompositions of cumene, ethylbenzene, and toluene, Makoto Hino, Mitsuhiko Kurashige,
Hiromi Matsuhashi and Kazushi Arata, Appl. Catal. A: General, 310, 190-193 (2006). Abstract

Biodiesel fuel production with solid amorphous-zirconia catalysis in fixed bed reactor, Satoshi Furuta,
Hiromi Matsuhashi and Kazushi Arata, Biomass and Bioenergy, 30, 870-873 (2006). Abstract

The surface structure of sulfated zirconia: Studies of XPS and thermal analysis, Makoto Hino, Mitsuhiko Kurashige,
Hiromi Matsuhashi and Kazushi Arata, Thermochimica Acta, 441, 35-41(2006). Abstract

Determination of Relative Acid Strength and Acid Amount of Solid Acids by Ar Adsorption,
Hiromi Matsuhashi and Ayumi Futamura, Catal. Today , 111, 338-342 (2006). Abstract

Synthesis of a ceramic acid of tungstated stannia more active than aluminosilicates for the esterification of n-octanoic acid with methanol, Makoto Hino, Satoshi Takasaki, Satoshi, Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Catal.Commun. , 7, 162-165 (2006). Abstract

Synthesis of a Ceramic Acid of Tungstated Alumina More Active Than Silica-Alumina for Decompositions of Cumene, Ethylbenzene, and Toluene, Makoto Hino,
Hiromi Matsuhashi, and Kazushi Arata, Catal. Lett., 107, 161-163 (2006). Abstract


2005

Reaction of Linear, Branched, and Cyclic Alkanes Catalyzed by Br?0?2nsted and Lewis Acids on H-Mordenite, H-Beta, and Sulfated Zirconia, Takemi Wakayama and
Hiromi Matsuhashi, J. Mol. Catal. A, J. Mol. Catal. A: , 239, 32-40 (2005). Abstract


2004

Biodiesel fuel production with solid amorphous zirconia catalysis in fixed bed reactor under atmospheric pressure, Satoshi Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Catal. Commun. , 5, 721-723 (2004). Abstract

Effect of preparation conditions on platinum metal dispersion and turnover frequency of several reactions over platinum-supported on alumina catalysts,
Hiromi Matsuhashi, Satoru Nishiyama, Hiroshi Miura, Koichi Eguchid, Koji Hasegawa, Yasuo Iizuka, Akira Igarashi, Naonobu Katada, Junya Kobayashi, Takashi Kubota, Tohru Mori, Kazuyuki Nakai, Noriyasu Okazaki, Masatoshi Sugioka, Takashi Umeki, Yoshiteru Yazawa and Daling Lu, Appl. Catal, A: General, 272, 329-338 (2004). Abstract

Catalytic action of sulfated tin oxide for etherification and esterification-comparison with sulfated zirconia, Satoshi Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Appl. Catal, A: General, 269, 187-191 (2004). Abstract

Distinction of Acid-type on Solid Acid Surface by Comparison of Adsorption Heats of Nitrogen and Argon,
Hiromi Matsuhashi, Keiko Yamagata, and Kazushi Arata, Chem. Lett., 2004, 554-555. Abstract, PDF

Measurement of the Relative Acid Strength and Acid Amount of Solid Acids by Argon Adsorption,
Hiromi Matsuhashi, and Kazushi Arata, Phys. Chem. Chem. Phys., in press. Abstract

Influence of Calcination Temperature on Surface Acidity of the Solid Superacid of Sulfated Alumina,
Hiromi Matsuhashi, Daishi Sato, and Kazushi Arata, React. Kinet. Catal. Lett., 81, 183 (2004). Abstract


2003

Isomerization of cycloheptane,cyclooctane,and cyclodecane catalyzed by sulfated zirconia - comparison with open-chain alkanes, Daishi Satoh,
Hiromi Matsuhashi, Hideo Nakamura and Kazushi Arata, Phys. Chem. Chem. Phys., 5, 4343-4349 (2003). Abstract, PDF

Synthesis of Solid Superacids and Their Activites for Reactions of Alkanes, Kazushi Arata,
Hiromi Matsuhashi, Makoto Hino, and Hideo Nakamura, Catal. Today, 81, 17-30 (2003). Abstract

Isomerization of Cycloheptane to Methylcyclohexane and Cyclooctane to Ethylcyclohexane Catalyzed by Sulfated Zirconia, Daishi Satoh,
Hiromi Matsuhashi, Hideo Nakamura, and Kazushi Arata, Catal. Lett., 89 , 105-107 (2003). Abstract


2002


2001

Catalytic Activities of Calcined Iron Sulfates for Hydrocracking of Model Compounds of Coal,
Hiromi Matsuhashi, Keiko Asari, and Kazushi Arata, Energy & Fuels, 15, 1523-1527 (2001). Abstract, PDF

Measurement of Heat of Argon Adsorption for The Evaluation of Relative Acid Strength of Some Sulfated Metal Oxides and H-type Zeolites,
Hiromi Matsuhashi, Takae Tanaka, and Kazushi Arata, J. Phys. Chem. B , 105, 9669-9671 (2001). Abstract, PDF

The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity Higher Than Sulfated Zirconia and Its Applications to Aldol Condensation and Benzoylation,
Hiromi Matsuhashi, Hidenori Miyazaki, Yuuki Kawamura, Hideo Nakamura, and Kazushi Arata, Chem. Mater. , 13, 3038-3042 (2001). Abstract, PDF

Effects of the Proton Content of ZSM-5 and the Amount of Pt on the Hydrodesulfurization Activity of Pt/ZSM-5, T. Kurosaka, M. Sugioka, and
H. Matsuhashi, Bull. Chem. Soc. Jpn., 74, 757-763 (2001). Abstract

The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity Higher Than Sulfated Zirconia,
H. Matsuhashi, H. Miyazaki, and K. Arata, Chem. Lett., 2001, 452-453. Abstract

Formation of Superbase Sites on Alkaline Earth Oxides by Dorping of Alkali Metals,
Hiromi Matsuhashi, Masakazu Oikawa, and Kazushi Arata, Langmuir, 16, 8201 (2000). Abstract

Formation of Acid Sites in Orderd Pores of FMS-16 by Modification with Sulfated Zirconia,
Hiromi Matsuhashi, Michiko Tanaka, Hideo Nakamura, and Kazushi Arata, Appl. Catal. A: General , 208, 1-5 (2001). Abstract


2000

Mukaiyama Aldol Reaction of 1-Trimethylsilyloxy-1-cyclohexene with Benzaldehyde over Solid Superacids with Preferential Syn Selectivity, Hideo Nakamura,
Hiromi Matsuhashi,and Kazushi Arata, Synlett, 2000, 668-670. Abstract

Temperature Programmed Desorption of Argon for Evaluation of Surface Acidity of Solid Superacids,
Hiromi Matsuhashi and Kazushi Arata, Chem. Commun, 2000, 387-388. Abstract